One-shot ultraspectral imaging with reconfigurable metasurfaces

One-shot spectral imaging that can obtain spectral information from thousands of different points in space at one time has always been difficult to achieve. Its realization makes it possible to get spatial real-time dynamic spectral information, which is extremely important for both fundamental scientific research and various practical applications. In this study, a one-shot ultraspectral imaging device fitting thousands of micro-spectrometers (6336 pixels) on a chip no larger than 0.5 cm$^2$, is proposed and demonstrated. Exotic light modulation is achieved by using a unique reconfigurable metasurface supercell with 158400 metasurface units, which enables 6336 micro-spectrometers with dynamic image-adaptive performances to simultaneously guarantee the density of spectral pixels and the quality of spectral reconstruction. Additionally, by constructing a new algorithm based on compressive sensing, the snapshot device can reconstruct ultraspectral imaging information ($\Delta\lambda$/$\lambda$~0.001) covering a broad (300-nm-wide) visible spectrum with an ultra-high center-wavelength accuracy of 0.04-nm standard deviation and spectral resolution of 0.8 nm. This scheme of reconfigurable metasurfaces makes the device can be directly extended to almost any commercial camera with different spectral bands to seamlessly switch the information between image and spectral image, and will open up a new space for the application of spectral analysis combining with image recognition and intellisense

Use of facile mechanochemical method to functionalize carbon nanofibers with nanostructured polyaniline and their electrochemical capacitance

A facile approach to functionalize carbon nanofibers [CNFs] with nanostructured polyaniline was developed via in situ mechanochemical polymerization of polyaniline in the presence of chemically treated CNFs. The nanostructured polyaniline grafting on the CNF was mainly in a form of branched nanofibers as well as rough nanolayers. The good dispersibility and processability of the hybrid nanocomposite could be attributed to its overall nanostructure which enhanced its accessibility to the electrolyte. The mechanochemical oxidation polymerization was believed to be related to the strong Lewis acid characteristic of FeCl3 and the Lewis base characteristic of aniline. The growth mechanism of the hierarchical structured nanofibers was also discussed. After functionalization with the nanostructured polyaniline, the hybrid polyaniline/CNF composite showed an enhanced specific capacitance, which might be related to its hierarchical nanostructure and the interaction between the aromatic polyaniline molecules and the CNFs

Effect of 5/6 Nephrectomized Rat Serum on Epithelial-to-Mesenchymal Transition In Vitro

Objective: To investigate whether the 5/6 nephrectomized (5/6Nx) rats’ 12-week serum could lead to tubular epithelial-to-mesenchymal transition (EMT) and its molecular mechanism, so as to probe the potential stimulation from circulation in chronic progressive kidney disease. Methods: A total of 24 Sprague Dawley (SD) rats were randomly divided into two groups: sham operation group (sham group) and 5/6Nx group. Rats were killed 12 weeks after surgery to obtain 5/6Nx rats’ 12-week serum. Then we detected the expression of E-cadherin in renal tubular epithelial cells of the remaining kidney and we investigated whether the 12th week serum of 5/6Nx rats could cause HK-2 (human kidney proximal tubular cell line) cells to transdifferentiate into fibroblasts. Results: Our data confirmed that E-cadherin expression decreased significantly in the remaining kidney at 12 weeks, and the 5/6Nx rats’ 12-week serum could suppress E-cadherin protein and mRNA expression (p < 0.05). We also found that the 5/6Nx rats’ 12-week serum could upreg-ulate ZEB1, β-catenin, and wnt3 protein expression (p < 0.05). Conclusions: Our results demonstrated that the 5/6Nx rats’ 12-week serum could suppress the expression of E-cadherin in HK-2 cells. It was partially through modulating the increase of ZEB1. The loss of E-cadherin could lead β-catenin to localize to the cytoplasm and nucleus, and feed into the Wnt signaling pathway. It means that the pathogenic serum in chronic kidney disease (CKD) plays an important role in the loss of renal function and turns to be a new avenue of research with potential clinical implications

Ozone Pollution in Chinese Cities: Spatiotemporal Variations and Their Relationships with Meteorological and Other Pollution Factors (2016–2020)

With the acceleration of urbanization, ozone (O3) pollution has become increasingly serious in many Chinese cities. This study analyzes the temporal and spatial characteristics of O3 based on monitoring and meteorological data for 366 cities and national weather stations throughout China from 2016 to 2020. Least squares linear regression and Spearman’s correlation coefficient were computed to investigate the relationships of O3 with various pollution factors and meteorological conditions. Global Moran’s I and the Getis–Ord index Gi* were adopted to reveal the spatial agglomeration of O3 pollution in Chinese cities and characterize the temporal and spatial characteristics of hot and cold spots. The results show that the national proportion of cities with an annual concentration exceeding 160 μg·m−3 increased from 21.6% in 2016 to 50.9% in 2018 but dropped to 21.5% in 2020; these cities are concentrated mainly in Central China (CC) and East China (EC). Throughout most of China, the highest seasonal O3 concentrations occur in summer, while the highest values in South China (SC) and Southwest China (SWC) occur in autumn and spring, respectively. The highest monthly O3 concentration reached 200 μg·m−3 in North China (NC) in June, while the lowest value was 60 μg·m−3 in Northeast China (NEC) in December. O3 is positively correlated with the ground surface temperature (GST) and sunshine duration (SSD) and negatively correlated with pressure (PRS) and relative humidity (RHU). Wind speed (WIN) and precipitation (PRE) were positively correlated in all regions except SC. O3 concentrations are significantly differentiated in space: O3 pollution is high in CC and EC and relatively low in the western and northeastern regions. The concentration of O3 exhibits obvious agglomeration characteristics, with hot spots being concentrated mainly in NC, CC and EC

Amino-Functionalized Titanium Based Metal-Organic Framework for Photocatalytic Hydrogen Production

Photocatalytic hydrogen production using stable metal-organic frameworks (MOFs), especially the titanium-based MOFs (Ti-MOFs) as photocatalysts is one of the most promising solutions to solve the energy crisis. However, due to the high reactivity and harsh synthetic conditions, only a limited number of Ti-MOFs have been reported so far. Herein, we synthesized a new amino-functionalized Ti-MOFs, named NH2-ZSTU-2 (ZSTU stands for Zhejiang Sci-Tech University), for photocatalytic hydrogen production under visible light irradiation. The NH2-ZSTU-2 was synthesized by a facile solvothermal method, composed of 2,4,6-tri(4-carboxyphenylphenyl)-aniline (NH2-BTB) triangular linker and infinite Ti-oxo chains. The structure and photoelectrochemical properties of NH2-ZSTU-2 were fully studied by powder X-ray diffraction, scanning electron microscope, nitro sorption isotherms, solid-state diffuse reflectance absorption spectra, and Mott&ndash;Schottky measurements, etc., which conclude that NH2-ZSTU-2 was favorable for photocatalytic hydrogen production. Benefitting from those structural features, NH2-ZSTU-2 showed steady hydrogen production rate under visible light irradiation with average photocatalytic H2 yields of 431.45 &mu;mol&middot;g&minus;1&middot;h&minus;1 with triethanolamine and Pt as sacrificial agent and cocatalyst, respectively, which is almost 2.5 times higher than that of its counterpart ZSTU-2. The stability and proposed photocatalysis mechanism were also discussed. This work paves the way to design Ti-MOFs for photocatalysis

Enhancing for Bagasse Enzymolysis via Intercrystalline Swelling of Cellulose Combined with Hydrolysis and Oxidation

To overcome the biological barriers formed by the lignin&ndash;carbohydrate complex for releasing fermentable sugars from cellulose by enzymolysis is both imperative and challenging. In this study, a strategy of intergranular swelling of cellulose combined with hydrolysis and oxidation was demonstrated. Pretreatment of the bagasse was evaluated by one bath treatment with phosphoric acid and hydrogen peroxide. The chemical composition, specific surface area (SSA), and pore size of bagasse before and after pretreatment were investigated, while the experiments on the adsorption equilibrium of cellulose to cellulase and reagent reuse were also performed. Scanning electron microscopy (SEM) and high-performance liquid chromatography (HPLC) were employed for microscopic morphology observations and glucose analysis, respectively. The results showed that pretreated bagasse was deconstructed into cellulose with a nanofibril network, most of the hemicellulose (~100%) and lignin (~98%) were removed, and the SSA and void were enlarged 11- and 5-fold, respectively. This simple, mild preprocessing method enhanced cellulose accessibility and reduced the biological barrier of the noncellulose component to improve the subsequent enzymolysis with a high glucose recovery (98.60%)

Analysis of special technical problems of wireless charging at UUV docking stations and a new underwater electromagnetic coupler

In order to solve the problem of insufficient range of autonomous underwater vehicles, underwater docking stations deployed on the seabed can wirelessly charge autonomous underwater vehicles through recyclers. Compared with traditional wireless charging of electric vehicles, wireless charging based on underwater docking stations has many special technical problems that need to be further understood and deciphered. This paper introduces the basic functions of the docking system and the docking process, and then focuses on the following three aspects of wireless charging at docking stations: firstly, the design of the coupler to suit the underwater vehicle and the complex marine environment, the coupler mechanism should match the shape and structure of the underwater vehicle, and the coupler should have a high resistance to deflection; secondly, the influence of the seawater medium on the wireless charging system. The impact of seawater medium on the wireless charging system is analysed, and the equivalent circuit model considering seawater eddy currents and the equivalent circuit model considering cross-connecting capacitance effects are established respectively; thirdly, the design of communication-independent wireless charging system. The existing eddy current loss calculation methods are analysed for the key technical problem of eddy current loss in seawater. A new type of electromagnetic coupler is proposed, the structural characteristics of the coupler are introduced and the simulation results show that the new coupler has a strong anti-deflection capability

The threshold reduction of SRS in deuterium by multi-pass configuration

Stimulated Raman scattering (SRS) in compressed D-2 gas pumped with nanosecond laser radiation at 1064 nm in a multi-pass configuration has been studied. The influence of D2 pressure and pass number on Raman thresholds and the conversion efficiencies for the first Stokes (S1) and second Stokes (S2) components has been investigated. It is shown that multi-pass configuration is very efficient for the substantial reducing of SRS thresholds for both S1 and S2 components and increasing their conversion efficiencies. In our work, the S1 threshold is approximately one order of magnitude lower than that reported in previous studies; the S1 conversion efficiency reached (56.1 perpendicular to 4.4)% at pump energy of 33 mJ. The lowest S2 threshold in the experiment is 15 mJ (with a peak power of 3 MW), and the S2 conversion efficiency reaches (32.9 +/- 3.8)%. (C) 2016 Elsevier B.V. All rights reserved

Analysis of frequency bifurcation and frequency splitting of IPT system under overcoupling

Wireless power transfer has gradually become a promising way for the charging of electric vehicles (EVs) and the design of a high efficiency and high stability charging system is inevitable. Inductive power transfer (IPT) systems, as one of the most important method to realize wireless power transfer, usually work under weak coupling conditions and obtain high power transmission efficiency through resonance compensation circuits. In the case of reduced power transmission distance, the IPT system will enter an over-coupled state, causing the system output power to change drastically and the system to detune, and frequency bifurcation and frequency splitting will also occur. This paper first theoretically deduces the root cause of the output power variation of several typical topological IPT systems under over-coupled conditions, and then analyzes their frequency bifurcation and frequency splitting characteristics by numerical analysis methods, which can provide a reference for the design of IPT systems. Finally, the theory of this paper is verified by simulation and a 2 kW test prototype